The 32-year-old Swede outstripped local favourite Fabian Cancellara by less than two seconds on the 34.3km course.
Maxime Monfort, also of RadioShack-Nissan, finished in third.
Rui Costa of Movistar Team defended his overall lead, finishing eighth at 41 seconds down; meanwhile, Roman Kreuziger (Astana) moved up second place.
Robert Gesink (Rabobank) is now in third, with Alejandro Valverde (Movistar) fourth and Frank Schleck (RadioShack-Nissan) fifth.
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